师资队伍
高分子材料
蒋选丰
姓名：蒋选丰
职称：教 授
出生日期：1982年10月
地址：尊龙凯时(中国)人生就是搏!7004室
E-mail: jxf19821023@126.com
研究兴趣：
(1) 超分子簇合物催化剂的可控自组装及其在光电器件、生物成像和绿色催化等方面的应用研究；
(2) 负载金属有机聚合物多孔材料的设计与模块化组装合成及其高效绿色催化水解脱硫性能研究。
二、蒋选丰教授学术贡献和研究方向简介
蒋选丰教授课题组科研工作聚焦在有机-金属超分子簇合物催化剂（人工自组装酶）、手性超分子囚笼、稀土主-客体复合物以及有机多孔聚合物（框架）等功能分子材料的精准自组装合成和性能开发。在此基础上，课题组成功将上述超分子/高分子功能材料应用到高效绿色催化脱硫，细胞成像和环境污染物的传感、吸附和分离等潜在应用领域，并取得了一系列研究成果。目前，相关成果分别在国际化学和材料领域知名期刊《Nature Chemistry》、《Chem》、《Journal of the American Chemical Society》（JACS，2014；2017；2019）、《Angewandte Chemie International Edition》(2025)、《Small Structures》(封面论文)、《Journal of Hazardous Materials》、《Chemical Engineering Journal》、 《Journal of Materials Chemistry A》、《Chemistry of Materials》和《Inorganic Chemistry》上发表论文50余篇，并获得多项中国发明专利。另外, 课题组与美国达特茅斯学院柯晨峰教授课题组长期保持学术交流和合作，相关合作成果在Cell出版社子刊《Chem》上发表论文2篇（Chem, 2021；2022）。作为项目负责人，独立主持基金项目6项，包括：国家自然科学基金面上项目和湖北省杰出青年基金项目。蒋选丰博士在超分子功能材料方面的研究兴趣与代表性研究成果包括：
（1）新颖钯（II）基有机聚合物多孔材料的设计、制备与催化水解脱硫性能研究。
2017年，蒋选丰教授利用一系列顺式水溶性双核金属钯（II）超分子簇合物催化剂，首次实现了在水溶液中室温常压条件下高效可循环催化水解二硫化碳（CS2）和羰基硫（COS）脱硫（产率>95%）。这项原创性成果为石油天然气中含硫分子的高效绿色脱硫净化技术开辟了新思路和途径。在该研究领域，部分成果以蒋选丰教授作为论文唯一第一作者发表在国际化学顶尖期刊《自然化学》(Nature Chemistry, 2017, 9, 188-193)上，并获得中国发明专利四项(授权专利号：ZL 201610344390.3, ZL 201910565125.1, ZL 202111447947.3, ZL 202211136244.3)。中国国家自然科学基金委员会以新闻头条的形式在其官网上对该成果进行实时报道，认为其开发的这项技术成果是绿色高效低温水解脱硫领域突破性进展和原创性成果。
独立工作后，课题组采用模块化共价组装策略将钯（II）配合物催化剂砖块与多功能有机交联单元共价组装成有机聚合物多孔材料（POPS）。这类有机聚合物多孔材料表现出高化学稳定性和孔洞可修饰性，并且金属活性中心在有机多孔材料限域空间内可进行多中心协同催化作用，从而实现非均相室温常压活化水解裂解二硫化碳和羰基硫脱硫。该项目研究成果可为石油和天然气的绿色高效水解脱硫提供新的思路和可能途径。目前，部分研究成果以全文形式发表在化学工程和环境科学领域权威期刊上 (Xuanfeng Jiang(通讯作者), et al., Palladium-anchored calix[4]Arene-derived porous organic polymer towards efficient hydrolytic cleavage of carbon disulfide, Journal of Hazardous Materials, 2024, 474, 134808; Efficient hydrolytic desulfurization of carbon disulfide using palladium-anchored bipyridine and phenanthroline-based organic polymers under mild conditions, Chemical Engineering Journal, 2025, 505, 159606)。
（2）利用金属-金属成键作用作为自组装驱动力精确合成具有特异性结构的手性超分子囚笼、多核超分子簇合物，并应用于细胞成像、3D打印和光催化等领域。
利用含氮硫位点的杯芳烃配体作为连接子，与币金属（一价Cu、Ag和Au）配位模块自组装得到一系列含有金-金成键中心的超分子簇合物材料。这类金属有机超分子簇合物材料在细胞成像、荧光染料和传感、OLED发光材料、光催化以及“人工自组装酶”催化等方面有潜在应用价值。部分成果以全文形式发表在国际化学顶尖期刊《美国化学会志》上（Xuanfeng Jiang（第一或者通讯作者）, et al, Angewandte Chemie, 2025, 64, e202420499; JACS, 2014, 136(31), 10921-10929；Small Structures, 2022, 2100155; CrystEngComm, 2021, 23, 7179–7185; New Journal of Chemistry, 2021, 45, 8910–8917; Inorganica Chimica Acta, 2022, 530, 120676; Journal of Cluster Science, 2022, 33, 2545–2550; Journal of Solid State Chemistry, 2022, 306, 122811; Journal of Molecular Structure, 2022, 1263(5), 133120; Crystal Growth & Design, 2022, 22, 4926–4934; Inorganic Chemistry, 2022, 61, 14267–14274; Crystal Growth & Design, 2023, 23, 1477–1485; Dyes and Pigments, 2023, 214, 111209; Inorganic Chemistry, 2023, 62, 15403-15411; Inorganic Chemistry, 2023, 62, 2652–2662; Inorganica Chimica Acta, 2023, 544, 121213; Dyes and Pigments, 2024, 222, 111868; Chemistry of Materials, 2024, 36, 2027−2038; Journal of Solid State Chemistry, 2024, 330, 124464。Journal of Materials Chemistry A, 2024, 12, 6634–6643; Crystal Growth & Design, 2024, 24, 6710-6718;
（3）金属簇基单晶态有机共价交联超分子框架材料的模块化自组装、结构调控与性能研究。
结合COFs和HOFs, SOFs的优点，运用单晶到单晶转化交联方法（SCSC），成功实现了晶体内部高度有序地光照诱导共价交联，最终合成了一类具有更高的化学稳定性的高单晶态有机共价框架材料（hydrogen-bonded cross-linked organic frameworks，HcOFs）。这类单晶态超分子框架材料最大特点是具有宏观可视弹性，可以高效吸附富集水中放射性碘。该项目中部分成果发表在国际化学顶尖期刊《美国化学会志》上（JACS, 2017, 139 (21), 7172; JACS, 2019, 141, 10915; Chem, 2021; Microporous and Mesoporous Materials, 2022, 345, 112261; Chemistry Letters, 2022, 51, 902-905; Journal of Environmental Chemical Engineering, 2024, 12, 112394；Microporous and Mesoporous Materials, 2024; Journal of Hazardous Materials, 2024等)。基于此策略，课题组采用主-客体作用、配位键和金属成键作为驱动力，模块化分级自组装成含有高核原子簇的单晶态有机共价交联超分子框架材料，并研究这材料的微观晶体结构和功能。
三、蒋选丰教授代表性论文成果和承担的科研项目
3.1 部分代表性学术论文和发明专利
(1) Qing-Ya Sun; Hui-Zhen He; Ying Zhou; Yu-Peng Dai; Ping Shang*; Xuan-Feng Jiang*, Photocatalytic Hydroxylation and Oxidative Coupling Reactions Mediated by Multinuclear Au(I) Supramolecular Clusters. Angewandte Chemie International Edition, 2025, 137, e202420499.
(2) Xuan--Feng Jiang; Hui Huang; Yun-Feng Chai; Tracy Lynn Lohr; Shu-Yan Yu; Wenzhen Lai; Yuan-Jiang Pan; Massimiliano Delferro; Tobin J. Marks; Hydrolytic Cleavage of Both CS2 Carbon Sulfur Bonds by Multinuclear Pd(II) Complexes at Room Temperature, Nature Chemistry, 2017, 9, 188-193.
(3) Xuan-Feng Jiang; Xunzhe Cui; Andrew J. E. Duncan; Liang Li; Russell P. Hughes; Richard J. Staples; Eugeny V. Alexandrov; Davide M. Proserpio; Yuyang Wu; Chenfeng Ke; Topochemical Synthesis of Single-Crystalline Hydrogen-Bonded Cross-Linked Organic Frameworks and Their Guest Induced Elastic Expansion, Journal of the American Chemical Society, 2019, 141(27),10915- 10923
(4) Xuan-feng Jang; Franky Ka-Wah Hau; Qing-Fu Sun; Shu-Yan Yu; Vivian Wing-Wah Yam; From {AuI…AuI}-Coupled Cages to the Cage-Built 2-D {AuI…AuI} Arrays: AuI…AuI Bonding Interaction Driven Self-Assembly and Their AgI Sensing and Photo-Switchable Behavior, Journal of the American Chemical Society, 2014, 136(31), 10921-10929.
(5) Yunxiao Lin, Xuan-feng Jiang(共同一作) et al, An Elastic Hydrogen-bonded Crosslinked Organic Framework for Effective Iodine Capture in Water. Journal of the American Chemical Society, 2017, 139, 7172-7175.
(6) Jayanta Samanta; Rick W Dorn; Wenlin Zhang; Xuanfeng Jiang; Mingshi Zhang; Richard Staples; Rossini Aaron; Chenfeng Ke*, An Ultra-dynamic Anion Cluster-based Organic Framework. Chem, 2022, 8, 253–267.
(7) Lin, Q.; Li, L.; Tang, M.; Uenuma, S.; Samanta, J.; Li, S.; Xuanfeng Jiang; Zou, L.; Ito, K.; Ke, C., Kinetic trapping of 3D-printable cyclodextrin-based poly(pseudo)rotaxane networks. Chem, 2021, 7, 2442-2459.
(8) Qing Huang; Xing-Yu Chen; Yu-Peng Dai; Guo-Kang Yang; Ping Shang*; Xuan-Feng Jiang*, Efficient Hydrolytic Desulfurization of Carbon Disulfide Using Palladium-Anchored Bipyridine and Phenanthroline-Based Organic Polymers under Mild Conditions, Chemical Engineering Journal, 2025, 505, 159606.
(9) Xiao-Qian Pu; Ping Shang; Xing-Yu Chen; Yu-Qing Xiao; Kai-Wen Jiang; Xuan-Feng Jiang*, Palladium-Anchored Calix[4]arene-Derived Porous Organic Polymer Towards Efficient Hydrolytic Cleavage of Carbon Disulfide, Journal of Hazardous Materials, 2024, 474, 134808.
(10) Yu-Hua Li; Hui-Ming Guan, Ping Shang*, Guo-Kang Yang, Kai-Kai Shu, Xing-Yu Chen*, Xuan-Feng Jiang*, Self-Assembly of Polynuclear Coordination Cage and Organic Dyes Adsorption Behavior in Water, Crystal Growth & Design, 2024, 24, 6710-6718.
(11) Xing-Yu Chen; Ping Shang; Yuan Zhan; Zhen-Guang Sun*; Xuan-Feng Jiang*, Full-Solar-Spectrum Absorption Photocatalytic Selective Oxidation Coupling of Benzylamine over a Nitrogen-Rich Conjugated Covalent Organic Framework, Microporous and Mesoporous Materials, 2024, 373, 113118.
(12) Ping Shang; Yu-Hua Li; Xing-Yu Chen; Yu-Qing Xiao; Xiao-Qian Pu; Kai-Wen Jiang; Xuan-Feng Jiang*, Dynamic {AuI…AuI}-Coupling Cluster-Based Coordination Capsule for Photocatalytic Benzylamine Oxidation, Journal of Materials Chemistry A, 2024, 12, 6634–6643.
(13) Yu-Qing Xiao; Ping Shang; Xing-Yu Chen; Xiao-Qian Pu; Kai-Wen Jiang; Xuan-Feng Jiang*, Confined Self-Assembly of Anionic [Cu8I14]6--Type Supramolecular Cluster and Performance Enhancement of Photo-Oxidation and Photo-Click Reaction, Chemistry of Materials, 2024, 36, 2027−2038.
(14) Yu-Qing Xiao; Ping Shang; Guo-Kang Yang; Xiao-Qian Pu; Kai-Wen Jiang; Zi-Wei Jiang; Can Wu*; Liu-Cheng Gui*; Ju-Ping Wang*; Xuan-Feng Jiang*, Ligand Conformation Directed Self-assembly of Heteroleptic Cu(I) Complexes and Luminescent Sensing Properties for Zn2+, Journal of Solid State Chemistry, 2024, 330, 124464.
(15) Ping Shang; Xiao-Qian Pu; Yu-Hua Li; Xing-Yu Chen; Zi-Wei Jiang; Yu-Qing Xiao; Xuan-Feng Jiang*, Anion-directed Cationic Supramolecular Dyes with Reversible Mechanochromism and Fabric Staining, Dyes and Pigments, 2024, 222, 111868.
(16) Zi-hao Jiang; Ping Shang; Zi-Wei Jiang; Tao Lu; Hui-Ming Guan; Yu-Hua Li; Liu-Cheng Gui; Xuan-Feng Jiang*, Self-Assembly of an Anionic [Cu5I8]3− Supramolecular Cluster Driven by Ion-Pair Interaction and Catalytic Properties, Inorganic Chemistry, 2023, 62, 15403-15411.
(17) Ping Shang; Zi-Hao Jiang; Rui Sun; Hui Yuan; Jie Yang; Qing Huang; Lin Song; Yu-Qing Xiao; Xiao-Qian Pu; Ting-Hong Huang*; Xuan-Feng Jiang*, The Anion-directed Self-Assembly of Tubular Helical Silver (I)-Based Coordination Polymers and The Adsorption Properties of Hazardous Substances, Inorganica Chimica Acta, 2023, 544, 121213.
(18) Jie Yang; Qing Huang; Hui Yuan; Ling Song; Xing-Yu Chen; Ping Shang; Xuan-Feng Jiang*, The Highly Selective and Sensitive Fluorescent Detection of SO2 Based on An Emissive Quinoline Derivative Probe, Dyes and Pigments, 2023, 214, 111209.
(19) Hui Yuan; Ping Shang; Jie Yang; Qing Huang; Ling Song; Xuan-Feng Jiang*, Anion-Directed Self-Assembly of Calix[4]arene-Based Silver(I) Coordination Polymers and Photocatalytic Degradation of Organic Pollutants, Inorganic Chemistry, 2023, 62, 2652-2662.
(20) Yao Wu; Zi-Hao Jiang; Jin-Yu Lei; Ping Shang; Xuan-Feng Jiang*, Self-Assembly and Mechanochromism Behavior of Gold(I) Supramolecular Cluster, Crystal Growth & Design, 2023, 23(3), 1477-1485.
(22) Ping Shang; Yao Wu; Zi-Hao Jiang; Hui-Zhen He; Qing Huang; Xiao-Qian Pu; Yu-Qing Xiao; Xuan-Feng Jiang*, Self-Assembly of Mechanoluminochromic Ladder-Shaped Gold(I) Clusters Promoted Using Cooperative Aurophilicity, Inorganic Chemistry, 2022, 61, 14267-14274.
(23) Yao Wu; Mo Xie; Ji-Kang Jin; Zhi-Yin Zhang; Han Hu; You-Ping Tian; Yu-Qing Xiao; Guo-Hong Ning*; Dan Li*; Xuan-Feng Jiang*, A Copper Iodide Cluster-Based Metal–Organic Polyhedra for Photocatalytic Click Chemistry, Small Structures, 2022, 3, 2100155.
(24) Yu-Qing Xiao; Ping Shang; Xiao-Qian Pu; Kai-Wen Jiang; Zi-Hao Jiang; Rui Sun; Xuan-Feng Jiang*, Multi-component Self-assembled Heteroleptic Cu(I) Complex with Defective Coordination Site as A Fluorescent Probe to Detect Zn2+, Journal of Molecular Structure, 2022, 1263, 133120.
(25) Qing Huang; Jia-Jun Zhu; Ling Song; Ping Shang; Xuan-Feng Jiang*, Highly Efficient Azide-alkyne Cycloaddition over CuI-modified Covalent Triazine Frameworks in Water, Microporous and Mesoporous Materials, 2022, 345, 112261.
(26) Jie Yang; Ping Shang; Hui Yuan; Ling Song; Qing Huang; Zi-Hao Jiang; Can Wu*; Xuan-Feng Jiang*, Regulated Adaptive Self-Assembly of Cu3I3 Supramolecular Clusters and their Photocatalytic Properties, Crystal Growth & Design, 2022, 22(8), 4926-4934.
(27) Rui Sun; Yu-Qing Xiao; Chu-Xing Hu; Ping Shang*; Ju-Ping Wang*; Xuan-Feng Jiang*, The Synthesis and Photocatalytic Properties of a Cuprous Iodide-based Coordination Polymer, Chem. Lett., 2022, 51, 902-905.
(28) Bang-Lian Xia; Zhan-Peng Jiang; Ya-Hui Xuan; Ping Shang*; Jia-Jun Zhu; Chu-Xing Hu; Yu-Qing Xiao; Zi-Hao Jiang; Xuan-Feng Jiang*, Self-assembly of Pd4L2 Supramolecular Cage and Permanganate Anion Adsorption Behavior in Water, Journal of Cluster Science, 2022, 33, 2545–2550.
(29) Chen-Lin Luo; Chu-Xing Hu; Ping Shang*; Guan-Zhao Wen; Jia-Jun Zhu; Ya-Hui Xuan; Bang-Lian Xia; Yu-Chen Liu; Zi-Hao Jiang; Geng Dong; Wei Zhang; Liu-Cheng Gui*; Xuan-Feng Jiang*, Synthesis of Heteroleptic Phosphine–copper(I) Complexes: Fluorescence Sensing and Catalytic Properties, New Journal of Chemistry, 2021, 45, 8910-8917.
(30) Hui Yuan; Ping Shang; Rui Sun; Jie Yang; Qing Huang; Ling Song; Can Wu*; Xuan-Feng Jiang*, Structural Transformation of Copper (II)-based Complexes Driven by N, S Cooperative Coordination and Iodine Adsorption Behavior, Journal of Solid State Chemistry, 2021, 36, 122811.
(31) Ping Shang; Geng Dong*; Xuan-Feng Jiang*, Hydrogen Bonds Promoted Formation of Eu(III)-based Host-guest Complex and Luminescence Properties, Inorganica Chimica Acta, 2021, 530, 120676.
(32) Chu-Xing Hu; Ya-Hui Xuan; Zi-Hao Jiang; Tao Lu; Jie Yang; Hui Yuan; You-Ping Tian; Zheng-Guang Sun*; Xuan-Feng Jiang*, Self-assembly of Cuprous Iodide Cluster-Based Calix[4]resorcinarenes and Photocatalytic Properties, CrystEngComm, 2021, 23, 7179-7185.
(33) Kai-Wen Jiang; Ping Shang; Xing-Yu Chen; Xiao-Qian Pu; Yu-Qing Xiao; Yuan Zhan*; Xuan-Feng Jiang*, Visible-light-induced Photocatalytic Degradation of Organic Contaminants by Silver(I)-loaded N-rich Porous Organic Polymers, Journal of Environmental Chemical Engineering, 2024, 12, 112394.
(34) 宋玲; 黄清; 蒋选丰*; 三嗪基有机多孔材料的制备及碘吸附性能研究, 化学工程, 2022, 50(8), 20-25. 第一标注
(35) 朱嘉君; 轩娅慧; 蒋选丰*; 单晶态有机聚合物多孔材料的研究进展, 中国材料进展, 2021, 40(9), 712-721. 北大中文核心期刊. 第一标注
3.2授权发明专利
(1) 蒋选丰; 胡楚星; 吴尧; 轩娅慧; 蒋展鹏; 刘青青; 多核CuI基超分子簇合物、合成方法及应用，2022-08-09至, 中国，ZL202011127346.X.
(2) 蒋选丰; 吴尧; 胡楚星; 蒋展鹏; 轩娅慧; 一种稀土超分子包合物及其制备方法和应用，2022-08-09至, 中国，ZL202010777775.5.
(3) 蒋选丰; 吴尧; 张司琪; 刘宇辰; 肖雨晴;一种多核有机-金属金（I）超分子簇合物及其合成方法与应用，2021-11-09至, 中国，ZL202010027273.0.
(4) 蒋选丰; 黄清; 尚萍; 一种负载银的有机聚合物多孔材料及其制备方法和应用，2023-12-13至2025-12-13, 中国，CN202211136244.3.
(5) 蒋选丰; 黄清; 蒋紫毫; 宋玲; 一种含钯的刚性有机聚合物多孔材料及其制备方法和应用，2023-10-03至2041-11-30, 中国，CN202111447947.3.
(6) 蒋选丰; 蒲晓倩; 尚萍; 含钯（Ⅱ）杯芳烃基有机多孔聚合物及其制备方法和应用，2023-12-05, 中国，202310962977.0.
3.3 承担的科研项目
(1)多核钯（II）杯芳烃基超分子聚合物多孔材料的模块化设计、合成及其催化水解脱硫性能研究。 国家自然科学基金面上项目，78.0万元，结题项目，2020年1月。
(2)新颖钯（II）基有机聚合物多孔材料的设计、制备与催化水解脱硫性能研究。 湖北省杰出青年基金项目，30.0万元，结题项目，2020年11月。
(3)新颖钯（II）基配合物催化剂的设计、制备与催化水解脱硫性能研究。湖北省催化材料制备及应用重点实验开放基金，2.0万元，结题，2019年5月。